Tuesday, August 17, 2010

THE FIRST ATOMIC THEORISTS

Democritus ("chosen of the people") was an Ancient Greek philosopher born in Abdera, Thrace, Greece. He was an influential pre-Socratic philosopher who formulated an atomic theory for the cosmos. His exact contributions are difficult to disentangle from his mentor Leucippus, as they are often mentioned together in texts. Their hypothesis on atoms is remarkably similar to modern science's understanding of atomic structure, and avoided many of the errors of their contemporaries. Largely ignored in Athens, Democritus was nevertheless well-known to his fellow northern-born philosopher Aristotle. Plato is said to have disliked him so much that he wished all his books burnt. Many consider Democritus to be the "father of modern science".


• Heraclitus taught that everything changes.

• Parmenides taught that change is logically impossible.

• The question is: How can matter change yet maintain its existence?

• The answer is: It is composed of indestructible units called atoms.

The ancient philosopher, Heraclitus, maintained that everything is in a state of flux. Nothing escapes change of some sort (it is impossible to step into the same river). On the other hand, Parmenides argued that everything is what it is, so that it cannot become what is not (change is impossible because a substance would have to transition through nothing to become something else, which is a logical contradiction). Thus, change is incompatible with being so that only the permanent aspects of the Universe could be considered real.

An ingenious escape was proposed in the fifth century B.C. by Democritus. He hypothesized that all matter (plus space and time) is composed of tiny indestructible units, called atoms. This idea seems motivated by the question of how finely one can go on cutting up matter. While Democritus performed no experiments and had only the flimsiest evidence for postulating the existence of atoms, his theory was kept alive by the Roman poet Lucretius which survived the Dark Ages to be discovered in 1417. The atoms in Democritus theory themselves remain unchanged, but move about in space to combine in various ways to form all macroscopic objects. Early atomic theory stated that the characteristics of an object are determined by the shape of its atoms. So, for example, sweet things are made of smooth atoms, bitter things are made of sharp atoms.

In this manner permanence and flux are reconciled and the field of atomic physics was born. Although Democritus' ideas were to solve a philosophical dilemma, the fact that there is some underlying, elemental substance to the Universe is a primary driver in modern physics, the search for the ultimate subatomic particle.

It was John Dalton, in the early 1800's, who determined that each chemical element is composed of a unique type of atom, and that the atoms differed by their masses. He devised a system of chemical symbols and, having ascertained the relative weights of atoms, arranged them into a table. In addition, he formulated the theory that a chemical combination of different elements occurs in simple numerical ratios by weight, which led to the development of the laws of definite and multiple proportions.

He then determined that compounds are made of molecules, and that molecules are composed of atoms in definite proportions. Thus, atoms determine the composition of matter, and compounds can be broken down into their individual elements.